DI-D-FRUCTOSE DIANHYDRIDES FROM THE PYROLYSIS OF INULIN

被引：21
|
作者：
BLIZE, AE [1 ]
MANLEYHARRIS, M [1 ]
RICHARDS, GN [1 ]
机构：
[1] UNIV MONTANA,SHAFIZADEH CTR WOOD & CARBOHYDRATE CHEM,MISSOULA,MT 59812
来源：
CARBOHYDRATE RESEARCH | 1994年 / 265卷 / 01期
关键词：
DI-D-FRUCTOSE DIANHYDRIDES; INULIN; PYROLYSIS OF; FRUCTOSE DIANHYDRIDES; DI-D-; PYROLYSIS;
D O I：
10.1016/0008-6215(94)00224-X
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Inulin was pyrolyzed in air to produce di-D-fructose dianhydrides (DFDAs) in similar to 26% yield, three of which were identified by MS, NMR, and comparison with literature data. The mass spectra of the per-O-trimethylsilyl derivatives of the DFDAs are discussed. A mechanism is proposed for the formation of DFDAs from inulin during pyrolysis.
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页码：31 / 39
页数：9
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