REACTIVITY OF MU-ETA-ALKYNE-BRIDGED DINUCLEAR IRIDIUM(II) COMPLEXES [IR(MU-S-TERT-BU)(CO)PA3]2RCCR(A = CH3, C6H5-R = CF3, CH3OC(O)) TOWARD HYDROGEN - AN INSIGHT INTO THE MECHANISM OF THESE REACTIONS BY A STUDY OF THEIR REACTION WITH FORMIC-ACID - A COMPETITIVE ELIMINATION OF TERT-BUSH AND OF ALKENE

被引：10

作者：

ELAMANE, M ^{[1
]}

MATHIEU, R ^{[1
]}

POILBLANC, R ^{[1
]}

机构：

[1] CNRS,CHIM COORDINAT LAB,F-31400 TOULOUSE,FRANCE

来源：

ORGANOMETALLICS | 1983年 / 2卷 / 11期

关键词：

D O I：

10.1021/om50005a023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：1618 / 1624

页数：7

共 6 条

[1] A SUCCESSION OF OXIDATIVE ADDITIONS AND REDUCTIVE ELIMINATIONS AS KEY PROCESSES IN THE REACTIONS OF MU-2-ETA-1 ALKYNE BRIDGED DINUCLEAR IRIDIUM-II COMPLEXES [IR(MU-S-TERT-BU)(CO)PA3]2RCCR (A = C6H5, CH3 - R = CH3OC(O), CF3) TOWARD TRIFLUOROACETIC-ACID
ELAMANE, M
MATHIEU, R
POILBLANC, R
NOUVEAU JOURNAL DE CHIMIE-NEW JOURNAL OF CHEMISTRY, 1982, 6 (04): : 191 - 196
[2] REACTIVITY OF DINUCLEAR IRIDIUM(II) COMPLEXES OF THE [IR(MU-ST-BU)(CO)PA3]2RCCR (A=C6H5, CH3, R=CF3, CH3OCO) CONTAINING AN ALKYNE LIGAND MU-2, N2 BOUND OPPOSITE TRIFLUOROACETIC-ACID
ELAMANE, M
POIBLANC, R
MATHIEU, R
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE PARTIE I-PHYSICOCHIMIE DES SYSTEMES LIQUIDES ELECTROCHIMIE CATALYSE GENIE CHIMIQUE, 1981, (11-1): : 395 - 395
[3] REACTIONS OF DINUCLEAR AND POLYNUCLEAR COMPLEXES .7. REACTION OF [(CO)3CO(MU-RC2R')CO(CO)3] (R = R' = CF3, CO2ME - R = CF3, C6H5 AND R' = H) WITH [(FECP(CO)2)2] - SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF DINUCLEAR AND TETRANUCLEAR MIXED-METAL COMPLEXES - ALKYNE COORDINATION AND SCISSION BY A TETRAMETALLIC FRAMEWORK - CRYSTAL-STRUCTURES OF [CO3FECP(MU-4-ETA-2-C = CHCF3)(ETA-6-C7H8)(MU-CO)2(CO)4] AND [CO3FECP2(MU-4-ETA-2-C=CCF3)(MU-CO)(CO)5]
RUMIN, R
ROBIN, F
PETILLON, FY
MUIR, KW
STEVENSON, I
ORGANOMETALLICS, 1991, 10 (07) : 2274 - 2285
[4] STUDY OF THE REACTIVITY OF THE NITRILES RCN (R = CH3, C6H5) TOWARD THE UNSATURATED (PPH3)2(CO)HRE(MU-H)3RUH(PPH3)2 COMPLEX - REVERSIBLE HYDROGEN ELIMINATION (R = ME) OR HYDROMETALLATION REACTIONS (R = C6H5)
HE, ZG
NEIBECKER, D
LUGAN, N
MATHIEU, R
ORGANOMETALLICS, 1992, 11 (02) : 817 - 821
[5] STUDY OF THE REACTIVITY OF [FE2(CO)6(MU-CO)(MU-C(C6H5)C(C6H5)H)]- TOWARD THE CH3OC(O)C=CC(O)OCH3 AND CF3C=CCF3 ALKYNES - CRYSTAL-STRUCTURE OF THE PRODUCTS RESULTING FROM 2 DIFFERENT MODES OF COMBINATION OF THE ALKYNES WITH THE BRIDGING LIGANDS [FE2(CO)6(MU-C(C(O)OCH3)C(C(O)OCH3)C(O)C(C6H5)C(C6H5)H)]- AND [FE2(CO)6(MU-C(C6H5)C(C6H5)C(CF3)C(CF3)H)]-EN
ROS, J
SOLANS, X
FONTALTABA, M
MATHIEU, R
ORGANOMETALLICS, 1984, 3 (07) : 1014 - 1020
[6] Novel amido-bridged dinuclear iridium(III) and iridium(II) complexes. Synthesis and characterization of [Cp*Ir(mu(2)-NHC6H4R-p)(3)IrCp*]Cl (Cp* = eta(5)-C5Me5; R = Me, H, Cl, CF3), [Cp*Ir{(mu(2)-NH)(2)C10H6-1,8}(mu(2)-X)IrCp*]X (X = Cl, Br), Cp*Ir{(mu(2)-NH)(2)C10H6-1,8}IrCp*, and [Cp*Ir{(mu(2)-NH)(2)C10H6-1,8}(mu(2)-H)IrCp*]O2CCF3
Matsuzaka, H
Ariga, K
Kase, H
Kamura, T
Kondo, M
Kitagawa, S
Yamasaki, M
ORGANOMETALLICS, 1997, 16 (21) : 4514 - 4516

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