SPONTANEOUS FORMATION OF STABLE PHOSPHINO(SILYL)-CARBENES FROM UNSTABLE DIAZO-COMPOUNDS

被引：52
|
作者：
GILLETTE, GR
BACEIREDO, A
BERTRAND, G
机构：
[1] UNIV PAUL SABATIER,CNRS,CHIM COORDINAT LAB,UP 8241,205 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE
[2] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 12期
关键词：
D O I：
10.1002/anie.199014291
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The carbene-like compounds 1, which are formed almost quantitatively from phosphanyldiazomethanes already at T less-than-or-equal-to 35-degrees-C if the tetramethylpiperidine (tmp)-R residue is one of the substituents on the phosphorus, are stable for several weeks in solution. With the exception of 1 a, the compounds 1 react with tBuNC to give the ketenimines 2. a, R = NiPr2, R' = Me; b, R = NMe2, R' = Me; c, R = NMe2,R' = iPr; d, R = Ph, R' = Me.
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页码：1429 / 1431
页数：3
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