NEW SYNTHESIS OF POLYAROMATICS THROUGH OXIDATIVE POLYMERIZATION BY USING METAL-COMPLEXES WITH AIR

被引：0
|
作者：
TSUCHIDA, E
YAMAMOTO, K
NISHIDE, H
机构：
[1] Department of Polymer Chemistry, Waseda University, Tokyo
来源：
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1992年 / 59卷
关键词：
D O I：
10.1002/masy.19920590103
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The oxidative polymerization provides a new synthetic route to polyaromatics. Poly(p-phenylene sulfide) (PPS) is produced by oxidative polymerization of thiophenol with a vanadyl complex catalyst. The metal complexes act as an efficient catalyst of oxygen oxidative polymerization. The polymerization to yield PPS is discussed especially focusing on the catalytic mechanism of the complexes.
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页码：1 / 16
页数：16
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