CARBENES IN MATRICES - REACTIONS AND REARRANGEMENTS

被引：23
|
作者：
SANDER, WW
PATYK, A
BUCHER, G
机构：
[1] Organisch-Chemisches Institut der Universität, 6900 Heidelberg
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1990年 / 222卷 / 1-2期
关键词：
D O I：
10.1016/0022-2860(90)80004-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Carbenes and silylenes with a variety of substituents have been isolated and characterized in low temperature matrices. Reactions of these species with small molecules, especially 3O2, have been studied. The structure of the primary addition products as well as the reactivity as a function of the spin-state (triplet T or singlet S) is discussed. © 1990.
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页码：21 / 31
页数：11
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