CHEMISTRY OF CROWN THIOETHER COMPLEXES OF LOW-VALENT 2ND-ROW TRANSITION-METALS

被引：7
|
作者：
YOSHIDA, T
ADACHI, T
UEDA, T
机构：
[1] Department of Chemistry, Faculty of Integarted Arts and Sciences, University of Osaka Prefecture, Sakai
来源：
PURE AND APPLIED CHEMISTRY | 1990年 / 62卷 / 06期
关键词：
D O I：
10.1351/pac199062061127
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Preparation, structures, and reactions of 14- and 16-membered quadridentate crown thioethers complexes, trans-Mo(N2)2Me8[16]aneS4, cis-and trans-RuCl2L and RhL+ (L=R4[14]aneS4, R8[16]aneS4; R=H, Me) are described emphasizing the novel features of crown thioethers vs. phosphines. The most prominent electronic property of the crown thioethers is pπ donor ability. The factors determining the reactivities of these complexes such as ring size and conformational effects of the macrocycles and geometrical effect of the complexes are discussed. © 1990 IUPAC
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页码：1127 / 1130
页数：4
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