REACTIONS OF ACRYLIC-ACID WITH FLUOROALKANOYL PEROXIDES - THE FORMATION OF ACRYLIC-ACID OLIGOMERS CONTAINING 2 FLUOROALKYLATED END-GROUPS

被引：25

作者：

SAWADA, H ^{[1
]}

MINOSHIMA, Y ^{[1
]}

NAKAJIMA, H ^{[1
]}

机构：

[1] NIPPON OIL & FATS CORP,TSUKUBA RES LAB,TSUKUBA,IBARAKI 30026,JAPAN

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 65卷 / 1-2期

关键词：

D O I：

10.1016/S0022-1139(00)80491-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fluoroalkylated acrylic acid oligomers were obtained by oligomerizations of acrylic acid with fluoroalkanoyl peroxides. Elemental analyses for fluorine showed that these oligomers contain two fluoroalkylated end-groups in one oligomeric molecule. Perfluoro-oxa-alkyl radicals produced by the decomposition of the corresponding peroxides have been demonstrated as being more stable than perfluoroalkyl radicals, and their higher stabilities explain the formation of higher molecular weight in the perfluoro-oxa-alkylated acrylic acid oligomers.

引用

页码：169 / 173

页数：5

共 50 条

[1] THE STRUCTURE OF ACRYLIC-ACID MONTMORILLONITE AND ACRYLIC-ACID KAOLINITE COMPLEXES
ZGADZAI, LK
VARFOLOMEEVA, EK
BOLSHEDVOROVA, GL
VLASOV, VV
[J]. COLLOID JOURNAL OF THE USSR, 1979, 41 (04): : 663 - 666
[2] ACRYLIC-ACID CHLORINATION
MOVSUMZADE, EM
MAMEDOV, MG
SHIKHEEV, IA
LAPIN, VB
[J]. KHIMICHESKAYA PROMYSHLENNOST, 1980, (04): : 204 - 206
[3] SYNTHESIS OF BUTADIEN - ACRYLIC-ACID CO-OLIGOMERS
STRUMIA, MC
BERTORELLO, H
[J]. ANALES DE LA ASOCIACION QUIMICA ARGENTINA, 1983, 71 (01): : 129 - 137
[4] GAS-CHROMATOGRAPHIC PROCEDURE FOR DETERMINATION OF ACRYLIC-ACID DIMER IN GLACIAL ACRYLIC-ACID
BRYANT, DR
TAYLOR, CE
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1976, 172 (SEP3): : 2 - 2
[5] ACRYLIC-ACID POPCORN POLYMERS
BREITENBACH, JW
KAUFFMAN.HF
[J]. MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1974, 175 (09): : 2597 - 2604
[6] OXIDATION OF PROPANE TO ACRYLIC-ACID
AI, M
[J]. CATALYSIS TODAY, 1992, 13 (04) : 679 - 684
[7] THIENYLDICHLOROPHOSPHINE REACTION WITH ACRYLIC-ACID
KHAIRULLIN, VK
ALIEV, RZ
[J]. ZHURNAL OBSHCHEI KHIMII, 1974, 44 (08): : 1683 - 1688
[8] COPOLYMERIZATION OF MULTIMETHACRYLATE WITH ACRYLIC-ACID
JANTAS, R
[J]. POLYMER INTERNATIONAL, 1993, 32 (04) : 357 - 360
[9] GRAFTING OF ACRYLIC-ACID ON COLLAGEN
VASILEV, MP
MAKSIMOV, AM
[J]. RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 1994, 67 (03) : 464 - 465
[10] GENETIC TOXICOLOGY OF ACRYLIC-ACID
MCCARTHY, KL
THOMAS, WC
AARDEMA, MJ
SEYMOUR, JL
PUTMAN, DL
YANG, LL
CURREN, RD
VALENCIA, R
[J]. FOOD AND CHEMICAL TOXICOLOGY, 1992, 30 (06) : 505 - 515

← 1 2 3 4 5 →