SILYLATIVE CYCLOCARBONYLATION OF ACETYLENIC BONDS CATALYZED BY RH-4(CO)(12) - AN EASY ACCESS TO BICYCLO[3.3.0]OCTENONE SKELETONS

被引：31
|
作者：
MATSUDA, I
ISHIBASHI, H
II, N
机构：
[1] Department of Applied Chemistry, School of Engineering, Nagoya University, Chikusa, Nagoya
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 02期
关键词：
D O I：
10.1016/0040-4039(94)02182-B
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A rhodium-catalyzed cyclopentenone annulation is found in the reaction of two moles of phenylacetylene and (t)BuMe(2)SiH under CO pressure. This type of CO incorporation is applied to the construction of bicyclo[3.3.0]octenone frameworks from 1,6-diynes.
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页码：241 / 244
页数：4
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