SYNTHESIS AND ANIONIC RING-OPENING POLYMERIZATION OF 1-GERMA-1,1-DIMETHYL[3,4,C]THIENOCYCLOPENTANE

被引：5
|
作者：
ZHOU, SQ
WEBER, WP
MAZEROLLES, P
LAURENT, C
机构：
[1] UNIV SO CALIF,DP & KB LOKER HYDROCARBON RES INST,DEPT CHEM,LOS ANGELES,CA 90089
[2] UNIV TOULOUSE 3,ORGANOMET LAB,UA 477,F-31062 TOULOUSE,FRANCE
来源：
POLYMER BULLETIN | 1990年 / 23卷 / 06期
关键词：
D O I：
10.1007/BF01033102
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
1-Germa-1,1-dimethyl[3,4, c]thienocyclopentane (I) has been prepared from 3-germa-3,3-dimethyl-7-thiabicyclo[3,3,0]oct-1-ene (II)1 by oxidation with dichorodicyanoquinone (DDQ). Treatment of I with a catalytic amount of n-butyllithium and HMPA in THF yields poly(1-germa-1,1-dimethyl[3,4, c]thienopentane) (III).[Figure not available: see fulltext.] © 1990 Springer-Verlag.
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页码：583 / 587
页数：5
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