H/HE MOLECULES IN STRONG ELECTRIC-FIELDS

被引：7
|
作者：
GRUNDLER, W
STEINKE, T
WALTHER, P
机构：
[1] Department of Chemistry, Humboldt University Berlin, Berlin, DDR-1080
来源：
JOURNAL OF COMPUTATIONAL CHEMISTRY | 1990年 / 11卷 / 05期
关键词：
D O I：
10.1002/jcc.540110503
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Floating spherical Gaussian orbitals are used within a split‐shell description to calculate the properties of H, He, He+, H2, H+2, HeH+, and H+3 in a strong uniform electric field. Accurate polarizabilities including their field strength dependence are obtained with two basis functions at most. Critical field strengths for ionization and deprotonation are determined for different orientations of molecules. Electron tunneling is described within the time dependent approach using floating Gaussian orbitals also. Copyright © 1990 John Wiley & Sons, Inc.
引用
收藏
页码：548 / 559
页数：12
相关论文
共 50 条
  • [1] INHIBITION OF VORTEX NUCLEATION IN HE II BY STRONG ELECTRIC-FIELDS
    MCCLINTOCK, PVE
    MOSS, FE
    BOWLEY, RM
    [J]. JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1980, 13 (21): : L503 - L509
  • [2] PHOTOIONIZATION SPECTRUM OF H IN STRONG DC ELECTRIC-FIELDS
    NG, K
    YAO, D
    NAYFEH, MH
    [J]. PHYSICAL REVIEW A, 1987, 35 (06): : 2508 - 2517
  • [3] PROPERTIES OF MOLECULES IN ELECTRIC-FIELDS
    SCHWEIG, A
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1972, 11 (11) : 1033 - +
  • [4] ELECTRIC-FIELDS AROUND MOLECULES
    HALL, GG
    SMITH, CM
    [J]. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1988, 48 : 293 - 303
  • [5] SPATIAL ORIENTATION OF MOLECULES IN STRONG ELECTRIC-FIELDS AND EVIDENCE FOR PENDULAR STATES
    FRIEDRICH, B
    HERSCHBACH, DR
    [J]. NATURE, 1991, 353 (6343) : 412 - 414
  • [6] MAGNETORESISTANCE OF SEMICONDUCTORS IN STRONG ELECTRIC-FIELDS
    KACHLISHVILI, ZS
    [J]. SOVIET PHYSICS SEMICONDUCTORS-USSR, 1972, 6 (03): : 487 - +
  • [7] GENERATION OF STRONG ELECTRIC-FIELDS IN THUNDERSTORMS
    LATHAM, J
    [J]. TRANSACTIONS-AMERICAN GEOPHYSICAL UNION, 1977, 58 (08): : 813 - 813
  • [8] PAIR CREATION IN STRONG ELECTRIC-FIELDS
    AOYAMA, H
    KOBAYASHI, M
    [J]. PROGRESS OF THEORETICAL PHYSICS, 1980, 64 (03): : 1045 - 1057
  • [9] MULTIPLE TRAPPING IN STRONG ELECTRIC-FIELDS
    ESIPOV, SE
    [J]. PHYSICAL REVIEW B, 1991, 44 (15): : 7930 - 7934
  • [10] EFFECTS OF STRONG ELECTRIC-FIELDS ON RESONANT STRUCTURES IN H- PHOTODETACHMENT
    BRYANT, HC
    CLARK, DA
    BUTTERFIELD, KB
    FROST, CA
    SHARIFIAN, H
    TOOTOONCHI, H
    DONAHUE, JB
    GRAM, PAM
    HAMM, ME
    HAMM, RW
    PRATT, JC
    YATES, MA
    SMITH, WW
    [J]. PHYSICAL REVIEW A, 1983, 27 (06): : 2889 - 2912
12345