REDOX CHEMICAL CORE MANIPULATION OF [OS18HG3C2(CO)42]2- - SYNTHESIS AND CRYSTAL-STRUCTURE OF THE CLUSTER [OS18HG2C2(CO)42]4-

被引：22
|
作者：
GADE, LH
JOHNSON, BFG
LEWIS, J
CONOLE, G
MCPARTLIN, M
机构：
[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND
[2] UNIV N LONDON,SCH CHEM,LONDON N7 8DB,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 22期
关键词：
D O I：
10.1039/dt9920003249
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The extrusion of metallic mercury from [Os18Hg3C2(CO)42]2- 1 by reduction has been studied and the tetraanionic cluster [Os18HgC2(CO)42]4- 3 isolated and characterised. The structure of the [N(PPh3)2]+ salt of 3 has been established by a single-crystal X-ray structure analysis. Oxidation of 3 with [Fe-(eta5-C5H5)2]BF4 yielded the corresponding tri- and di-anionic clusters 4 and 2. The clusters 1-4 were found to be interrelated by reversible photochemical and redox-chemical transformations. This reactive behaviour is reflected in the results of an electrochemical study of 1 by cyclic voltammetry.
引用
收藏
页码：3249 / 3254
页数：6
相关论文
共 50 条
  • [1] Removing a second mercury atom from [Os18Hg3C2(CO)42]2-: synthesis of [Os18HgC2(CO)42]4- and crystal structure of [PPh3H]3[Os18HgHC2(CO)42]
    [J]. J Chem Soc Dalton Trans, 5 (597):
  • [2] Removing a second mercury atom from [Os(18)Ng(3)C(2)(CO)(42)](2-): Synthesis of [Os18HgC2(CO)(42)](4-) and crystal structure of [PPh(3)H](3)[Os18HgHC2(CO)(42)]
    Gade, LH
    Johnson, BFG
    Lewis, J
    McPartlin, M
    Scowen, IJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (05): : 597 - 601
  • [3] ISOLATION AND X-RAY STRUCTURE DETERMINATION OF THE CLUSTER DIANION [OS20HG(C)2(CO)48]2-, AND THE IDENTIFICATION OF THE CLUSTER PREVIOUSLY REPORTED WITH THIS STOICHIOMETRY AS [OS18HG3(C)2(CO)42]2-
    GADE, LH
    JOHNSON, BFG
    LEWIS, J
    MCPARTLIN, M
    POWELL, HR
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (02) : 110 - 113
  • [4] [(PH3P)2N]2[OS18HG2C2(CO)42] A PHOTOCHEMICALLY GENERATED HIGH-NUCLEARITY CLUSTER WHICH REVERSIBLY INCORPORATES METALLIC MERCURY INTO ITS METAL CORE
    CHARALAMBOUS, E
    GADE, LH
    JOHNSON, BFG
    KOTCH, T
    LEES, AJ
    LEWIS, J
    MCPARTLIN, M
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (10): : 1137 - 1139
  • [5] PHOTOCHEMISTRY OF LARGE OSMIUM CLUSTERS - VISIBLE LASER EXCITATION OF [PPN]2[OS18HG3C2(CO)42] AND ITS CORRESPONDING RADICAL-ANION COMPLEX
    KOTCH, T
    LEES, AJ
    GADE, L
    JOHNSON, BFG
    LEWIS, J
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 289 - INOR
  • [6] ELECTRONIC-STRUCTURE OF OSMIUM CLUSTER CARBONYLS - OS3(CO)12,OS6(CO)18,[OS6(CO)18]2-,[OS10C(CO)24]2-
    BULLETT, DW
    [J]. CHEMICAL PHYSICS LETTERS, 1987, 135 (4-5) : 373 - 376
  • [7] Systemic syntheses of [Hg{M(CO)4}2]2-, [Hg{M(CO)4}]x (M = Fe, Ru, Os), and structures of [Hg{M(CO)4}2]2- (M = Ru, Os)
    Chun, SH
    Meyers, EA
    Liu, FC
    Lim, S
    Shore, SG
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 563 (1-2) : 23 - 29
  • [8] THE SYNTHESIS AND X-RAY STRUCTURE-ANALYSIS OF THE DIANION [RU18(C)2(CO)42HG3]2-, THE 1ST OCTADECARUTHENIUM CLUSTER
    BAILEY, PJ
    JOHNSON, BFG
    LEWIS, J
    MCPARTLIN, M
    POWELL, HR
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (20) : 1513 - 1515
  • [9] REDOX CHEMISTRY OF THE CLUSTER [OS10C(CO)24]2-
    DRAKE, SR
    BARLEY, MH
    JOHNSON, BFG
    LEWIS, J
    [J]. ORGANOMETALLICS, 1988, 7 (04) : 806 - 812
  • [10] THE REACTION OF HG(O2CCF3)2 WITH [OS6(CO)18] - SYNTHESIS AND CRYSTAL-STRUCTURES OF 2 NEW PRODUCTS - [HOS5HG2(CO)15(O2CCF3)3] AND CIS-[OS4(CO)12(O2CCF3)2]
    DIEBOLD, MP
    JOHNSON, BFG
    LEWIS, J
    SAHARAN, VP
    MCPARTLIN, M
    POWELL, HR
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 405 (02) : C25 - C28
12345