SYNTHESIS OF ALDEHYDES FROM CARBOXYLIC-ACIDS VIA N-METHOXYIMIDOYL BROMIDES - DEOXIMATION OF O-METHYLOXIMES

被引：0

作者：

SAKAMOTO, T ^{[1
]}

KIKUGAWA, Y ^{[1
]}

机构：

[1] JOSAI DENT UNIV,FAC PHARMACEUT SCI,1-1 KEYAKIDAI,SAKADO,SAITAMA,JAPAN

来源：

SYNTHESIS-STUTTGART | 1993年 / 06期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aldehydes are synthesized by hydrogenation and subsequent deoximation of substituted N-methoxyalkanimidoyl bromides, which are prepared in one pot by reaction of the corresponding carboxylic acids with methoxyamine and triphenylphosphine carbon tetrabromide. Regeneration of aldehydes and ketones from O-methyloximes under mild conditions is also described.

引用

页码：563 / 564

页数：2

共 37 条

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