Kinetic Study of Esterification of Acetic Acid with nbutanol and isobutanol Catalyzed by Ion Exchange Resin

被引：33
|
作者：
Toor, Amrit Pal [1 ]
Sharma, Mamta [1 ]
Kumar, Ghansyam [1 ]
Wanchoo, R. K. [1 ]
机构：
[1] Panjab Univ, Univ Inst Chem Engn & Technol, Chandigarh 160014, India
来源：
BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS | 2011年 / 6卷 / 01期
关键词：
Heterogeneous catalysis; Esterification; acetic acid: Ion exchange resin; Amberlyst; 15;
D O I：
10.9767/bcrec.6.1.665.23-30
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Esters are an important pharmaceutical intermediates and very useful perfumery agents. In this study the esterification of acetic acid with n-butanol and iso-butanol over an acidic cation exchange resin, Amberlyst 15 were carried out. The effects of certain parameters such as temperature, catalyst loading, initial molar ratio between reactants on the rate of reaction were studied. The experiments were conducted in a stirred batch reactor in the temperature range of 351.15 K to 366.15K. Variation of parameters on rate of reaction demonstrated that the reaction was intrinsically controlled. The activation energy for the esterification of acetic acid with n-butanol and iso butanol is found to be 28.45 k J/mol and 23.29 kJ/mol respectively. (C) 2011 BCREC UNDIP. All rights reserved.
引用
收藏
页码：23 / 30
页数：8
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