COPOLYMERIZATION OF ETHYLENE AND BUTADIENE WITH SUPPORTED TITANIUM CATALYST

被引：14
|
作者：
SUN, LX
LU, ZJ
LU, Y
LIN, SG
机构：
[1] Ahongshan Univ, China
来源：
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS | 1988年 / 26卷 / 10期
关键词：
Butadiene--Polymerization; -; Catalysts--Titanium; Copolymers--Synthesis; Ethylene--Polymerization; Polymerization--Catalysts;
D O I：
10.1002/polb.1988.090261007
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The copolymerization of ethylene and butadiene with a supported titanium catalyst (TiCl4/MgCl2/EB/φ2$/SiCl2/AlEt3) is described. The resulting products were characterized by IR, 13C-NMR, x-ray diffraction, differential thermal analysis, electron microscopy, and solvent extraction. It was found that the butadiene units are substantially in trans-1,4 configuration and blocked sequences. Both ethylene and butadiene blocks form crystalline phases. The presence of unsaturated bonds made it possble to graft MMA and maleic anhydride. The influences of monomer composition, temperature, Al/Ti ratio, catalyst concentration, and solvents on the copolymerization were investigated.
引用
下载
收藏
页码：2113 / 2126
页数：14
相关论文
共 50 条
  • [1] Alternating copolymerization of ethylene and butadiene with a neodymocene catalyst
    Thuilliez, J
    Monteil, V
    Spitz, R
    Boisson, C
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (17) : 2593 - 2596
  • [2] EFFECT OF PHENYLDICHLOROMETHANE ON THE POLYMERIZATION AND COPOLYMERIZATION OF ETHYLENE ON A SUPPORTED TITANIUM-MAGNESIUM CATALYST
    IVANCHEV, SS
    KRYZHANOVSKII, AV
    GAPON, II
    PONOMAREVA, EL
    KINETICS AND CATALYSIS, 1990, 31 (02) : 313 - 317
  • [3] Study on complex-supported titanium catalyst for gas-phase homopolymerization and copolymerization of ethylene
    Zhang, Qixing
    Wang, Haihua
    Wang, Senhui
    Shiyou Huagong/Petrochemical Technology, 2000, 29 (03): : 187 - 191
  • [4] Kinetic inhomogeneity of copolymerization sites of butadiene and isoprene on titanium catalyst
    Taibulatov, P. A.
    Mingaleev, V. Z.
    Zakharov, V. P.
    Ionova, I. A.
    Monakov, Yu. B.
    POLYMER SCIENCE SERIES B, 2010, 52 (7-8) : 450 - 458
  • [5] Kinetic inhomogeneity of copolymerization sites of butadiene and isoprene on titanium catalyst
    P. A. Taibulatov
    V. Z. Mingaleev
    V. P. Zakharov
    I. A. Ionova
    Yu. B. Monakov
    Polymer Science Series B, 2010, 52 : 450 - 458
  • [6] Alternating copolymerization of ethylene with carbon monoxide on a supported palladium catalyst
    O. M. Chukanova
    Yu. M. Shul’ga
    G. P. Belov
    Polymer Science Series B, 2009, 51 : 283 - 290
  • [7] Alternating copolymerization of ethylene with carbon monoxide on a supported palladium catalyst
    Chukanova, O. M.
    Shul'ga, Yu. M.
    Belov, G. P.
    POLYMER SCIENCE SERIES B, 2009, 51 (7-8) : 283 - 290
  • [8] Ethylene and carbon monoxide copolymerization catalyzed by supported palladium catalyst
    Chukanova, Olga M.
    Alpherov, Kirill A.
    Belov, Gennadiy P.
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2010, 325 (1-2) : 60 - 64
  • [9] Ethylene-Butadiene Copolymerization and Ethylene-1-Hexene-Butadiene Terpolymerization with a MgCl2-Supported Ziegler-Natta Catalyst: Polymer Structure and Active Centers
    Akram, Muhammad Adnan
    Liu, Xiaoyu
    Fu, Zhisheng
    Fan, Zhiqiang
    CHEMISTRYSELECT, 2021, 6 (32): : 8288 - 8298
  • [10] SUPPORTED TITANIUM-MAGNESIUM CATALYST OF ETHYLENE POLYMERIZATION
    PAKHA, I
    NOVAKOVSKA, M
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1985, 27 (09): : 1840 - 1844
12345