(BEDT-TTF)2GACL4 - STRUCTURE, ELECTRICAL AND MAGNETIC-PROPERTIES

被引：10
|
作者：
KURMOO, M
ALLAN, M
FRIEND, RH
CHASSEAU, D
BRAVIC, G
DAY, P
机构：
[1] INST LAUE LANGEVIN,F-33042 GRENOBLE,FRANCE
[2] UNIV BORDEAUX 1,CRISTALLOG LAB,F-33405 TALENCE,FRANCE
[3] UNIV CAMBRIDGE,CAVENDISH LAB,CAMBRIDGE CB3 0HE,ENGLAND
来源：
SYNTHETIC METALS | 1991年 / 42卷 / 1-2期
关键词：
D O I：
10.1016/0379-6779(91)92032-D
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
We report the synthesis, crystal structure, electrical transport and magnetic properties of (BEDT-TTF)2GaCl4. It crystallises in a triclinic system, P1BAR, a = 31.911, b = 16.580, c = 6.645 angstrom, alpha = 98.15, beta = 85.60, gamma = 90.55-degrees, Z = 4 and V = 3470 angstrom 3 with stacks of twisted dimers. sigma-RT (parallel-to to c) = 0.1 Scm-1 and E(A) = 0.21 eV. The susceptibility is anisotropic; chi-(parallel-to to c) behaves as a 1D antiferromagnetic chain and chi-(perpendicular-to to c) is activated with E(A) approximately 9meV.
引用
收藏
页码：2127 / 2130
页数：4
相关论文
共 50 条
  • [1] ELECTRICAL AND MAGNETIC-PROPERTIES OF (BEDT-TTF)4NI(CN)4 COMPLEX
    TANAKA, M
    TAKEUCHI, H
    SANO, M
    ENOKI, T
    SUZUKI, K
    IMAEDA, K
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1989, 62 (05) : 1432 - 1435
  • [2] Antiferromagnetic Ordering in Organic Conductor λ-(BEDT-TTF)2GaCl4 Probed by 13CNMR
    Saito, Yohei
    Fukuoka, Shuhei
    Kobayashi, Takuya
    Kawamoto, Atsushi
    Mori, Hatsumi
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2018, 87 (01)
  • [3] ELECTRONIC AND MAGNETIC-PROPERTIES OF A TRIFLATE SALT OF BEDT-TTF, (BEDT-TTF)2CF3SO3
    MARSDEN, IR
    OBERTELLI, SD
    ALLAN, ML
    FRIEND, RH
    KURMOO, M
    ROSSEINSKY, MJ
    DAY, P
    SYNTHETIC METALS, 1991, 42 (1-2) : 2151 - 2154
  • [4] THE ELECTRICAL AND MAGNETIC-PROPERTIES OF A NOVEL 2-DIMENSIONAL ANTIFERROMAGNET BASED ON BEDT-TTF - THETA-(BEDT-TTF)(2)CU-2(CN)[N(CN)(2)](2)
    KOMATSU, T
    SATO, H
    NAKAMURA, T
    MATSUKAWA, N
    YAMOCHI, H
    SAITO, G
    KUSUNOKI, M
    SAKAGUCHI, K
    KAGOSHIMA, S
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1995, 68 (08) : 2233 - 2244
  • [5] Solvent-Included Ternary Charge-Transfer Salt (BEDT-TTF)2GaCl4(C6H5Cl)0.5, (BEDT-TTF = Bis(ethyelenedithio)-tetrathiafulvalene)
    Zhang, Bin
    Zhang, Yan
    CRYSTALS, 2013, 3 (01): : 112 - 119
  • [6] A BEDT-TTF COMPLEX INCLUDING A MAGNETIC ANION, (BEDT-TTF)3(MNCL4)2
    MORI, T
    INOKUCHI, H
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (02) : 591 - 593
  • [7] MAGNETIC-PROPERTIES OF THE ORGANIC SUPERCONDUCTOR BETA-(BEDT-TTF)2AUI2
    TALHAM, DR
    KURMOO, M
    DAY, P
    OBERTELLI, DS
    PARKER, ID
    FRIEND, RH
    JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1986, 19 (18): : L383 - L388
  • [8] Crystal structure and electrical conductivity of α"-[BEDT-TTF]12[Cu2Br4]3 (BEDT-TTF=bis(ethylenedithio)tetrathiafulvalene)
    Kubo, Kazuya
    Miyasaka, Hitoshi
    Yamashita, Masahiro
    PHYSICA B-CONDENSED MATTER, 2010, 405 (11) : S308 - S312
  • [9] Commensurate magnetic structure in κ-(BEDT-TTF)2X
    Miyagawa, K
    Kawamoto, A
    Uchida, K
    Kanoda, K
    PHYSICA B, 2000, 284 : 1589 - 1590
  • [10] Magnetic properties of (BEDT-TTF)(2)X with localized spins
    Yoneyama, N
    Miyazaki, A
    Enoki, T
    Saito, G
    SYNTHETIC METALS, 1997, 86 (1-3) : 2029 - 2030
12345