SPONTANEOUS ADDITION-REACTION OF N,7,7-TRICYANOBENZOQUINONE METHIDE IMINE WITH 1-[(TRIMETHYLSILYL)OXY]-1-CYCLOHEXENE

被引：1

作者：

ITOH, T

TANAKA, N

IWATSUKI, S

机构：

[1] Department of Chemistry for Materials, Faculty of Engineering, Mie University, Kamihama-cho

来源：

MACROMOLECULES | 1995年 / 28卷 / 02期

关键词：

D O I：

10.1021/ma00106a003

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Spontaneous reaction of N,7,7-tricyanobenzoquinone methide imine (BMI) with 1-[(tri-methylsilyl.)oxy]-1-cyclohexene (1) was carried out at 60 degrees C in acetonitrile with the concentration of BMI below and above its equilibrium monomer concentration, and reaction products were analyzed. On the basis of the structure of the reaction products sind H-1 NMR spectra observed in situ for the reactions of BMI with 1 and of 7,7,8,8-tetracyanoquinodimethane (TCNQ) with 1, the initiation mechanism and a driving force to determine the addition direction for the-intermediate formation are discussed.

引用

页码：421 / 424

页数：4