DIRECT OBSERVATION OF LONG-CHAIN ALKANE BILAYER FILMS ON GRAPHITE BY SCANNING TUNNELING MICROSCOPY

被引：100
|
作者：
WATEL, G
THIBAUDAU, F
COUSTY, J
机构：
[1] DSM, DRECAM, SRSIM
来源：
SURFACE SCIENCE | 1993年 / 281卷 / 1-2期
关键词：
D O I：
10.1016/0039-6028(93)90843-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The interface between a solution of hexatriacontane (n-C36H74) in decane and the basal plane of graphite has been studied by scanning tunneling microscopy at room temperature. For the first time, we show that a second layer which is rotated by 60-degrees with respect to the first layer may grow at the interface. We demonstrate that the carbon skeleton of the molecule is parallel to the graphite surface. We propose a model for the arrangement of the molecular layers and an explanation for the origin of the second layer rotation.
引用
收藏
页码：L297 / L302
页数：6
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