PERMSELECTIVITY OF FILMS PREPARED BY ELECTROPOLYMERIZATION OF 2,6-DIMETHYLPHENOL

被引：53

作者：

OHSAKA, T ^{[1
]}

HIROKAWA, T ^{[1
]}

MIYAMOTO, H ^{[1
]}

OYAMA, N ^{[1
]}

机构：

[1] TOKYO UNIV AGR & TECHNOL, DEPT APPL CHEM RESOURCES, KOGANEI, TOKYO 184, JAPAN

来源：

ANALYTICAL CHEMISTRY | 1987年 / 59卷 / 14期

关键词：

ELECTRIC MEASUREMENTS - ELECTROLYTES - Solutions - PHENOLS - Polymerization;

D O I：

10.1021/ac00141a004

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A selective permeability of the poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) films being prepared by electropolymerization of 2,6-dimethylphenol to the various redox species dissolved in the solution was investigated by means of hydrodynamic voltammetry at a rotating disk electrode. The selective permeability was found to be different for the PPO films prepared from the different electrolytic solutions. The PPO films, prepared from the basic methanolic solution, had a high selective permeability to hydrogen ion, but blocked the access of larger redox ions such as Fe(CN)//6**3** minus , Fe**2** plus , and (ethylenediaminetetraacetato)iron(III) (Fe(edta)** minus ) to the electrode surface.

引用

页码：1758 / 1761

页数：4

共 50 条

[1] STRUCTURE OF 2,6-DIMETHYLPHENOL AND 3,5-DIMETHYLPHENOL
GILLIERPANDRAUD, H
BECKER, P
LONGCHAM.F
ANTONA, D
COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1972, 275 (25): : 1495 - 1498
[2] POLYMERIZATION OF 2,6-DIMETHYLPHENOL ON SMECTITE SURFACES
SAWHNEY, BL
KOZLOSKI, RK
ISAACSON, PJ
GENT, MPN
CLAYS AND CLAY MINERALS, 1984, 32 (02) : 108 - 114
[3] 4-(TETRACYANOETHYL)2,6-DIMETHYLPHENOL
SMITH, B
PERSMARK, U
ACTA CHEMICA SCANDINAVICA, 1962, 16 (02): : 523 - &
[4] Enzymatic oxidative polymerization of 2,6-dimethylphenol
Ikeda, R
Sugihara, J
Uyama, H
Kobayashi, S
MACROMOLECULES, 1996, 29 (27) : 8702 - 8705
[5] REACTIONS OF THIONYL CHLORIDE WITH 2,6-DIMETHYLPHENOL
TAKIMOTO, HH
DENAULT, GC
JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (03): : 759 - &
[6] CONDENSATION OF 2,6-DIMETHYLPHENOL WITH GLYOXAL + WITH BENZIL
MCGOWAN, JC
WALKER, NC
ANDERSON, JM
RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1964, 83 (06): : 597 - &
[7] 2,6-DIMETHYLPHENOL - A NEW METABOLITE OF MEXILETINE
GRECHBELANGER, O
TURGEON, J
LALANDE, M
RESEARCH COMMUNICATIONS IN CHEMICAL PATHOLOGY AND PHARMACOLOGY, 1987, 58 (01): : 53 - 62
[8] ORTHO OXIDATION OF 2,6-DIMETHYLPHENOL WITH TRIFLUOROPEROXYACETIC ACID
MCCLURE, JD
JOURNAL OF ORGANIC CHEMISTRY, 1963, 28 (01): : 69 - &
[9] Luminescence quenching of tris(2,2′-bipyridine)ruthenium(II) by 2,6-dimethylphenol and 4-bromo-2,6-dimethylphenol in sol-gel-processed silicate thin films
Altamirano, M
Senz, A
Gsponer, HE
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 270 (02) : 364 - 370
[10] New promising antioxidants based on 2,6-dimethylphenol
Kemeleva, E. A.
Vasyunina, E. A.
Sinitsina, O. I.
Khomchenko, A. S.
Gross, M. A.
Kandalintseva, N. V.
Prosenko, A. E.
Nevinskii, G. A.
RUSSIAN JOURNAL OF BIOORGANIC CHEMISTRY, 2008, 34 (04) : 499 - 509

← 1 2 3 4 5 →