CONDITIONS FOR THE APPLICABILITY OF THE BODENSTEIN METHOD IN CHEMICAL-KINETICS

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FRANKKAMENETSKII, DA
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O6 [化学];
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0703 ;
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Conditions for the applicability of the Bodenstein method for reactions in case of any kinetics and any number of intermediates result in three inequalities. If the rate of elementary processes depends on the concentration of reactive, species, as it is usual in Chemical kinetics, only the first one is important, requiring that the lifetime of the intermediate be small compared to the time interval of the reaction.
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页码:907 / 914
页数:8
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