AN UNUSUALLY STABLE SUPPORTED BIS(CYCLOPENTADIENYL)TITANIUM DICHLORIDE-TRIALKYLALUMINUM CATALYST SYSTEM FOR ETHYLENE POLYMERIZATION

被引:42
|
作者
SATYANARAYANA, G [1 ]
SIVARAM, S [1 ]
机构
[1] NATL CHEM LAB,DIV POLYMER CHEM,POONA 411008,MAHARASHTRA,INDIA
关键词
D O I
10.1021/ma00069a046
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We now report for the first time a simple synthesis of a MGCl2 supported Cp2TiCl2 catalyst which shows significant activity for ethylene polymerization in the presence of trialkylaluminum and a kinetic behavior distinctly different from that of an unsupported metallocene catalyst.
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页码:4712 / 4714
页数:3
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