PHOTOCATALYTIC DEGRADATION OF CHLOROPHENOLS TO CO2 AND HCL WITH POLYOXOTUNGSTATES IN AQUEOUS-SOLUTION

被引：72

作者：

MYLONAS, A ^{[1
]}

PAPACONSTANTINOU, E ^{[1
]}

机构：

[1] DEMOKRITOS NATL CTR SCI RES,INST PHYS CHEM,GR-15310 ATHENS,GREECE

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 92卷 / 03期

关键词：

CHLOROPHENOLS; DEGRADATION; PHOTOCATALYSIS; POLYOXOTUNGSTATES; TUNGSTEN;

D O I：

10.1016/0304-5102(94)00083-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Homogeneous oxygenated aqueous solutions of chlorophenols, undergo photodegradation (lambda > 320 nm) to CO2 and Cl- by polyoxometalates W10O324-, PW12O403-, and SiW12O404-. Mineralization takes place, also, in the absence of dioxygen but the process is more than an order of magnitude slower. In presence of dioxygen the effectiveness of these catalysts compares with TiO2 suspension.

引用

页码：261 / 267

页数：7

共 50 条

[1] Photocatalytic degradation of chlorophenols to CO2 and HCl with polyoxotungstates in aqueous solution
[J]. Mylonas, A., 1600, Elsevier Science Publishers B.V., Amsterdam, Netherlands (92):
[2] On the mechanism of photocatalytic degradation of chlorinated phenols to CO2 and HCl by polyoxometalates
Mylonas, A
Papaconstantinou, E
[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1996, 94 (01) : 77 - 82
[3] ESTIMATION OF CO2 REDUCTION ENERGY IN AQUEOUS-SOLUTION AND CO2 AFFINITY TO ELECTRON
BERDNIKOV, VM
[J]. ZHURNAL FIZICHESKOI KHIMII, 1975, 49 (11): : 2988 - 2989
[4] Degradation of chlorophenols in aqueous solution by γ-radiation
Hu, Jun
Wang, Jianlong
[J]. RADIATION PHYSICS AND CHEMISTRY, 2007, 76 (8-9) : 1489 - 1492
[5] DEGRADATION OF ANTIFLAMMIN-2 IN AQUEOUS-SOLUTION
WOLFE, JL
LEE, GE
POTTI, GK
GALLELLI, JF
[J]. JOURNAL OF PHARMACEUTICAL SCIENCES, 1994, 83 (12) : 1762 - 1764
[6] Plasma induced degradation of chlorophenols in an aqueous solution
Saitama Inst of Technology, Saitama, Japan
[J]. Thin Solid Films, 1-2 (123-127):
[7] Plasma induced degradation of chlorophenols in an aqueous solution
Tezuka, M
Iwasaki, M
[J]. THIN SOLID FILMS, 1998, 316 (1-2) : 123 - 127
[8] Photo-degradation of chlorophenols in the aqueous solution
Czaplicka, Marianna
[J]. JOURNAL OF HAZARDOUS MATERIALS, 2006, 134 (1-3) : 45 - 59
[9] Highly efficient and selective photocatalytic CO2 to CO conversion in aqueous solution
Chai, Xiaomin
Huang, Hai-Hua
Liu, Huiping
Ke, Zhuofeng
Yong, Wen-Wen
Zhang, Ming-Tian
Cheng, Yuan-Sheng
Wei, Xian-Wen
Zhang, Liyan
Yuan, Guozan
[J]. CHEMICAL COMMUNICATIONS, 2020, 56 (27) : 3851 - 3854
[10] DEGRADATION OF BUSULFAN IN AQUEOUS-SOLUTION
HASSAN, M
EHRSSON, H
[J]. JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 1986, 4 (01) : 95 - 101

← 1 2 3 4 5 →