SYNTHESIS OF 6,13-DIHYDROXYIMINO-5,12-DIMETHYL-7,14-DIOXO-1,4,8,11-TETRAAZACYCLOTETRADECA-4,11-DIENE

被引：0
|
作者：
LIN, CH
机构：
来源：
JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 1993年 / 40卷 / 05期
关键词：
1,4,8,11-TETRAAZACYCLOTETRADECA-4,11-DIENE;
D O I：
10.1002/jccs.199300077
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
6,13-dihydroxyimino-5,12-dimethyl-7,14-dioxo-1,4,8,11-tetraazacyclotetradeca-4,11-diene 2 was prepared by condensation of ethyl alpha-oximinoacetoacetate with ethylenediamine in tetrahydrofuran at room temperature. Reduction of 2 gave the corresponding 6,13-dihydroxyimino-5,12-dimethyl-7,14-dioxo-1,4,8,11-tetraazacyclotetradecane 3. Acylation of 2 afforded 6,13-bis(O-acetoxyimino)-5,12-dimethyl-7,14-dioxo-1,4,8,11-tetraazacyclotetradeca-4,11-diene 4. The structures of 2, 3 and 4 were determined by IR, NMR and mass spectroscopy.
引用
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页码：485 / 487
页数：3
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