NICKEL(II) COMPLEX DERIVED FROM 2-HYDROXY-3-METHOXYBENZALDEHYDE SEMICARBAZONE AND 2,2 '-BIPYRIDINE

被引：1
|
作者：
Vomisescu, Carolina [1 ,2 ]
Bourosh, Paulina [3 ]
Kravtsov, Victor [3 ]
Dragancea, Diana [1 ]
机构：
[1] Moldavian Acad Sci, Inst Chem, 3 Acad Str, MD-2028 Kishinev, Moldova
[2] Univ Acad Sci Modova, MD-2028 Kishinev, Moldova
[3] Moldavian Acad Sci, Inst Appl Phys, MD-2028 Kishinev, Moldova
来源：
CHEMISTRY JOURNAL OF MOLDOVA | 2013年 / 8卷 / 02期
关键词：
semicarbazone; binuclear nickel(II) complex; crystal structure;
D O I：
10.19261/cjm.2013.08(2).09
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of 2-hydroxy-3-methoxybenzaldehyde semicarbazone with Ni(NO3)(2)center dot 6H(2)O, in the presence of 2,2'-bipyridine, afforded a dinuclear complex (1). Crystal structure of 1 revealed the dinuclear complex, in which one nickel center is surrounded octahedrally by two monoanionic O,N,O-donor semicarbazone. The second nickel center also adopts an octahedral geometry created by two 2,2'- bipyridine ligands and the bridging phenolate oxygen of the monodeprotonated semicarbazones.
引用
收藏
页码：78 / 82
页数：5
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