INVESTIGATIONS OF THE V/O/RASO(3)(2-) SYSTEM - SOLVOTHERMAL SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF [(V2O3)(PH(6)AS(6)O(14))]

被引：19
|
作者：
SALTA, J [1 ]
CHANG, YD [1 ]
ZUBIETA, J [1 ]
机构：
[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 09期
关键词：
D O I：
10.1039/c39940001039
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of PPh4[VO2Cl2], with PhAsO(3)H(2) in acetonitrile for 36 h at 100 degrees C and autogenous pressure yields [(V2O3)(PhsAs(6)O(14))], an unusual cluster with a {V2O3}(4+) core straddled by the hexadentate ligand {Ph(6)As(6)O(14)}(4-) which forms via thermally induced condensation of PhAsO(3)H(2) groups.
引用
收藏
页码：1039 / 1040
页数：2
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