LIQUID-PHASE CATALYTIC-HYDROGENATION USING PALLADIUM ALLOY MEMBRANES

被引:21
|
作者
FARRIS, TS [1 ]
ARMOR, JN [1 ]
机构
[1] AIR PROD & CHEM INC,7201 HAMILTON BLVD,ALLENTOWN,PA 18195
关键词
ALKENES; CYLCOHEXENE; HYDROGENATION; MEMBRANES; PALLADIUM ALLOYS;
D O I
10.1016/0926-860X(93)80004-A
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The hydrogenation of several liquid alkenes was studied over Pd/Ru alloy membranes in either metal or glass membrane reactors. For cyclohexene, cyclo-octadiene, and octadecene as liquids, conversions of ca. 2-5% were common in contrast to the facile conversion of acetylenic alcohols.
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页码:25 / 32
页数:8
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