URANIUM SORPTION FROM CARBONATE SOLUTIONS BY INORGANIC SORBENTS .11. THERMODYNAMICS OF U-SORPTION BY THERMOXIDE-5 DURING SORPTION DESORPTION CYCLES

被引：0

作者：

NURIEV, AN

AKPEROV, GA

KOMAREVSKII, VM

MAMEDOV, RM

NOVIKOV, YP

机构：

来源：

SOVIET RADIOCHEMISTRY | 1991年 / 33卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The thermodynamics of U sorption on Thermoxide-5 from 20 to 65-degrees-C with various initial [U] (from 2.6.10(-5) to 8.4.10(-4) M) in marine-type carbonate solution at pH = 7.85 is studied during sorption-desorption cycles. The entropy, enthalpy, and free energy of U sorption change from cycle to cycle. The sorption is found to occur in two steps consisting of reversible (ion-exchange) and irreversible (chemosorption) steps.

引用

页码：187 / 190

页数：4

共 13 条

[1] SORPTION OF URANIUM FROM CARBONATE SOLUTIONS BY INORGANIC SORBENTS .12. KINETICS OF U-SORPTION BY THERMOXIDE-5 DURING SORPTION DESORPTION CYCLES
NURIEV, AN
AKPEROV, GA
KOMAREVSKII, VM
MAMEDOV, RM
NOVIKOV, YP
SOVIET RADIOCHEMISTRY, 1991, 33 (02): : 191 - 193
[2] STUDIES OF THE THERMODYNAMICS OF URANIUM SORPTION ON SORBENT THERMOXIDE-5
MAMEDOV, RM
NOVIKOV, YP
KOMAREWSKY, VM
MYASOEDOV, BF
SHARYGIN, LM
GONCHAR, VF
MALYCH, TG
RADIOCHEMICAL AND RADIOANALYTICAL LETTERS, 1982, 55 (02): : 107 - 112
[3] THE SORPTION OF URANIUM FROM CARBONATE-CONTAINING SOLUTIONS BY INORGANIC SORBENTS
NURIEV, AN
SHIK, EI
ABDULLAEVA, RS
SOVIET RADIOCHEMISTRY, 1985, 27 (06): : 719 - 723
[4] THE UPTAKE OF URANIUM FROM CARBONATE SOLUTIONS BY INORGANIC SORBENTS .7. THERMODYNAMICS OF SORPTION ON DISORDERED SORBENTS CONTAINING TITANIUM
MYASOEDOV, BF
NURIEV, AN
NOVIKOV, YP
KOMAREVSKII, VM
MAMEDOV, RM
SHARYGIN, LM
GONCHAR, VF
MALYKH, TG
SOVIET RADIOCHEMISTRY, 1984, 26 (03): : 265 - 268
[5] SORPTION OF URANIUM FROM CARBONATE CONTAINING SOLUTIONS BY INORGANIC SORBENTS .10. MECHANISM OF URANIUM SORPTION BY FIBERS PACKED WITH FINELY DIVIDED SORBENTS
MYASOEDOV, BF
NOVIKOV, YP
MIKHEEVA, MN
KOMAREVSKII, VM
MEZHIROV, MS
IDIATULOV, RK
FEDOROVA, AN
SOVIET RADIOCHEMISTRY, 1987, 29 (05): : 618 - 622
[6] SORPTION OF URANIUM FROM CARBONATE CONTAINING SOLUTIONS BY INORGANIC SORBENTS .9. KINETICS OF URANIUM SORPTION BY FIBERS PACKED WITH FINELY DIVIDED SORBENTS
MIKHEEVA, MN
MYASOEDOV, BF
NOVIKOV, YP
KOMAREVSKII, VM
MEZHIROV, MS
IDIATULOV, RK
FEDOROVA, AN
SOVIET RADIOCHEMISTRY, 1987, 29 (05): : 614 - 618
[7] Sorption of uranium from carbonate-containing solutions on inorganic sorbents. Kinetics and thermodynamics of uranium sorption on titanium-tin- and titanium-manganese-containing sorbents
Nuriev, AN
Akperov, GA
Mamedov, RM
Dzhabbarova, ZA
Ragimli, MA
Efendieva, SZ
RADIOCHEMISTRY, 1998, 40 (03) : 262 - 264
[8] THE SORPTION OF URANIUM FROM CARBONATE-CONTAINING SOLUTIONS BY MEANS OF INORGANIC SORBENTS .5. MECHANISM OF THE SORPTION OF URANIUM BY ALUMINUM ORTHO-PHOSPHATE
NOVIKOV, YP
KOMAREVSKII, VM
AKHMANOVA, MV
SOVIET RADIOCHEMISTRY, 1979, 21 (06): : 747 - 751
[9] RESEARCH ON THE SORPTION OF URANIUM FROM CARBONATE-CONTAINING SOLUTIONS BY INORGANIC SORBENTS .6. MECHANISM OF URANIUM SORPTION ON METATITANIC ACID
NOVIKOV, YP
KOMAREVSKII, VM
SOVIET RADIOCHEMISTRY, 1981, 23 (06): : 643 - 646
[10] THE SORPTION OF URANIUM FROM CARBONATE-CONTAINING SOLUTIONS BY MEANS OF INORGANIC SORBENTS .4. THE KINETICS OR URANIUM SORPTION BY ALUMINUM ORTHO-PHOSPHATE
NOVIKOV, YP
KOMAREVSKII, VM
SOVIET RADIOCHEMISTRY, 1979, 21 (06): : 744 - 747

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