PREPARATION OF SILYL ENOL ETHERS DERIVED FROM ALPHA-PHENYLSELENO ALDEHYDES AND ALPHA-PHENYLSELENO KETONES

被引：12

作者：

PONTHIEUX, S ^{[1
]}

OUTURQUIN, F ^{[1
]}

PAULMIER, C ^{[1
]}

机构：

[1] UNIV ROUEN,UFR SCI,IRCOF,SYNTH HETEROORGAN LAB,F-76821 MONT ST AIGNAN,FRANCE

来源：

TETRAHEDRON | 1995年 / 51卷 / 35期

关键词：

D O I：

10.1016/0040-4020(95)00532-D

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The best experimental conditions for the preparation of trimethylsilyl enol ethers 3 from alpha-phenylseleno aldehydes 1, compatible with a limited deselenenylation of the substrate, were studied. Starting from alpha-phenylseleno ketones 2, the enoxysilanes 4, bearing a vinylic PhSe group, are the major products when triethylamine is the base. Trimethylsilyl enol ethers 5 with an allylic PhSe group are also formed beside 4 when LDA or KH are used at lower temperatures.

引用

页码：9569 / 9580

页数：12

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