POLYDISPERSITY EFFECTS IN THE SYSTEM POLY(ETHYLENE GLYCOL) PLUS DEXTRAN PLUS WATER

被引:12
|
作者
GAUBE, J
HOCHEMER, R
KEIL, B
PFENNIG, A
机构
[1] Institut für Chemische Technologie, Technische Hochschule Darmstadt, D-6100 Darmstadt
来源
关键词
D O I
10.1021/je00010a005
中图分类号
O414.1 [热力学];
学科分类号
摘要
Tie lines in the system poly(ethylene glycol) (PEG) + dextran + water have been measured at 20-degrees-C. The apparent polydispersity of PEG was varied by mixing two essentially monodisperse PEG fractions in different ratios. The overall phase composition for a given tie line was changed to obtain phase ratios different from unity. The concentrations and molecular-weight distributions of all polymers in the coexisting liquid phases were determined using size-exclusion chromatography (SEC). The results are compared to those of systems containing monodisperse PEG with different molecular weights.
引用
收藏
页码:207 / 210
页数:4
相关论文
共 50 条
  • [1] Partition coefficients of proteins in poly(ethylene glycol) plus dextran plus water at 298 K
    Fele, L
    Fermeglia, M
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (02): : 331 - 334
  • [2] Solubility of carbon dioxide in monoethanolamine plus ethylene glycol plus water and monoethanolamine plus poly(ethylene glycol) plus water
    Song, JH
    Yoon, JH
    Lee, H
    Lee, KH
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (03): : 497 - 499
  • [3] Solubility of carbon dioxide in monoethanolamine plus ethylene glycol plus water and monoethanolamine plus poly(ethylene glycol) plus water at 333.2 K
    Song, JH
    Park, SB
    Yoon, JH
    Lee, H
    Lee, KH
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1997, 42 (01): : 143 - 144
  • [4] Interfacial tension of poly(ethylene glycol) plus salt plus water systems
    Wu, YT
    Zhu, ZQ
    Mei, LH
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (05): : 1032 - 1035
  • [5] Clouding feature for water plus betaine plus poly(ethylene glycol) plus Salt) quaternary mixtures
    You, Xiaoyan
    Qin, Wei
    Ding, Yuwen
    Dai, Youyuan
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233
  • [6] Partition coefficients of amino acids, peptides, and enzymes in dextran plus poly(ethylene glycol) plus water aqueous two-phase systems
    Kakisaka, K
    Shindou, T
    Ishidao, T
    Iwai, Y
    Arai, Y
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1998, 31 (06) : 991 - 995
  • [7] Measurement and correlation of partition coefficients of amino acids in dextran plus poly(ethylene glycol) plus water aqueous two-phase systems
    Zhou, F
    Kakisaka, K
    Ishidao, T
    Iwai, Y
    Arai, Y
    Furuya, T
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1997, 30 (02) : 349 - 353
  • [8] Liquid-liquid equilibrium of the poly(ethylene glycol) plus sodium nitrate plus water system at 298.15 K
    Graber, TA
    Taboada, ME
    Cartón, A
    Bolado, S
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2000, 45 (02): : 182 - 184
  • [9] Liquid-liquid equilibria for the poly(ethylene glycol) plus water plus copper sulfate system at different temperatures
    Mohsen-Nia, M.
    Rasa, H.
    Modarress, H.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (04): : 946 - 949
  • [10] Kinematic Viscosities of polyethylene glycol plus dextran plus water solutions
    Gündüz, U
    Dogan, ÖM
    CHEMICAL ENGINEERING COMMUNICATIONS, 2005, 192 (10-12) : 1586 - 1597