SYNERGISTIC SOLVENT-EXTRACTION OF COBALT(III) BY ACETYLACETONE MIXED WITH ALCOHOL, KETONE, ETHER AND TRIBUTYL-PHOSPHATE FROM ACETATE BUFFER SOLUTIONS

被引：0
|
作者：
ELNAGGAR, HA
SOMEDA, H
ABDELGAWAD, A
机构：
[1] Nuclear Research Center, Nuclear Chemistry Department, Atomic Energy Authority, Cairo
来源：
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES | 1992年 / 157卷 / 01期
关键词：
D O I：
10.1007/BF02039787
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The extraction of Co(III) has been studied from acetate medium by acetylacetone in CHCl3. The effect of adding different synergetic bases (S) like diisobutyl ketone, dibutyl ether, diisobutyl carbinol and tributyl phosphate was studied. The extracted species is Co(OH)2 (AcAc) . 2HAcAc by acetylacetone only while the species formed for the mixed extractants are Co(OH)2 (AcAc) . (HAcAc) (S)n where "n" = 1 or 2. The corresponding thermodynamic parameters were determined and discussed.
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页码：159 / 168
页数：10
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