SYNTHESIS, STRUCTURE AND REACTIONS OF A CARBON-DIOXIDE COMPLEX OF IRON(0) CONTAINING 1,2-BIS(DIETHYLPHOSPHINO)ETHANE LIGANDS

被引：36
|
作者：
KOMIYA, S
AKITA, M
KASUGA, N
HIRANO, M
FUKUOKA, A
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 09期
关键词：
D O I：
10.1039/c39940001115
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of [Fe(N-2)(depe)(2)] with carbon dioxide gives trigonal bipyramidal [Fe(eta(2)-CO2)(depe)(2)], where the coordinated CO2 lies on equatorial plane by an eta(2)-fashion and converts into dimethyl ether and [FeX(CO)(depe)(2)]X (X = I, OTf) on interaction with methyl halide or triflate.
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页码：1115 / 1116
页数：2
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