O-18 SCRAMBLING STUDIES IN THE SOLVOLYSIS OF ALPHA-(T-BUTYL)BENZYL TOSYLATES

被引：8
|
作者：
TSUJI, Y
YATSUGI, K
FUJIO, M
TSUNO, Y
机构：
[1] KYUSHU UNIV,INST FUNDAMENTAL RES ORGAN CHEM,HAKOZAKI,FUKUOKA 812,JAPAN
[2] KYUSHU UNIV,FAC SCI,DEPT CHEM,HAKOZAKI,FUKUOKA 812,JAPAN
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 09期
关键词：
D O I：
10.1016/0040-4039(95)00059-L
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The sulfonate O-18-scrambling during the solvolysis of alpha-(t-butyl)benzyl tosylates was investigated in typical solvents by C-13-NMR spectroscopy using O-18/O-16 isotope shift on the alkoxy C-13-NMR signals. The existence or extensive ion-pair return n comparable to product formation was explored in this k(c) solvolysis.
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页码：1461 / 1464
页数：4
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