C-13 CP-MAS NMR-SPECTRA AND FLUXIONAL BEHAVIOR OF (M2(ETA-HCCCME2)(CO)4(ETA-C5H5)2)+(BF4)-(M = MO, W) COMPLEXES IN THE SOLID-STATE

被引：7

作者：

GALAKHOV, MV ^{[1
]}

BAKHMUTOV, VI ^{[1
]}

BARINOV, IV ^{[1
]}

机构：

[1] MV LOMONOSOV STATE UNIV,DEPT CHEM,MOSCOW 117234,USSR

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1991年 / 29卷 / 05期

关键词：

(M2(ETA-HCCCME2)(CO)4(ETA-C5H5)2)+(BF4)-(M; MO; W); COMPLEXES; C-13 CP-MAS NMR; INTERNAL ROTATION;

D O I：

10.1002/mrc.1260290516

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Internal rotation about the C-2-C-3 bond was observed in the C-13 CP-MAS NMR spectra of the solid complexes [M2(eta-HC1C2C3Me2)(CO)4(eta-C5H5)2] + [BF4]- where M = Mo or W.

引用

页码：506 / 508

页数：3

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