STEREOSELECTIVE FORMATION OF A 2/1-MOLECULAR-COMPLEX BETWEEN ALPHA-CYCLODEXTRIN AND CARBAZOLE-VIOLOGEN LINKED COMPOUND WITH A LONG ALKYL CHAIN AS THE SPACER

被引：11

作者：

YONEMURA, H ^{[1
]}

NOJIRI, T ^{[1
]}

MATSUO, T ^{[1
]}

机构：

[1] KYUSHU UNIV, FAC ENGN, DEPT CHEM SCI & TECHNOL, FUKUOKA 812, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 11期

关键词：

D O I：

10.1246/cl.1994.2097

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Analysis of H-1 NMR spectra revealed a novel mode of complexation between alpha-cyclodextrial (CD) and a carbazole-viologen linked compound with 16 methylene units in the spacer. The complexation afforded a stable rotaxane-type CD complex, where two alpha-CDs encased the spacer chain. NOE experiments confirmed selective formation of unique isomer among four possible orientations of the encasing alpha-CD.

引用

页码：2097 / 2100

页数：4

共 2 条

[1] Effect of high magnetic fields on the reverse electron transfer process in an alpha-cyclodextrin inclusion complex of phenothiazine-viologen chain-linked compound
Fujiwara, Y
Aoki, T
Yoda, K
Cao, H
Mukai, M
Haino, T
Fukazawa, Y
Tanimoto, Y
Yonemura, H
Matsuo, T
Okazaki, M
[J]. CHEMICAL PHYSICS LETTERS, 1996, 259 (3-4) : 361 - 367
[2] THERMODYNAMIC PARAMETERS FOR FORMATION OF THROUGH-RING ALPHA-CYCLODEXTRIN COMPLEXES OF DONOR-ACCEPTOR LINKED COMPOUNDS - COMPARISON BETWEEN D2O AND H2O SOLUTIONS OF ANTHRACENE VIOLOGEN SYSTEMS WITH INTRAMOLECULAR CHARGE-TRANSFER ABSORPTION-SPECTRA
TOKI, A
YONEMURA, H
MATSUO, T
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1993, 66 (11) : 3382 - 3386

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