Crystal Structure of a Dinuclear Zinc(II) Complex with a Phenol-based Dinucleating Ligand

被引：0
|
作者：
Ito, Misaki [1 ]
Mitsuhashi, Ryoji [2 ]
Mikuriya, Masahiro [2 ]
Sakiyama, Hiroshi [1 ]
机构：
[1] Yamagata Univ, Fac Sci, Dept Mat & Biol Chem, 1-4-12 Kojirakawa, Yamagata 9908560, Japan
[2] Kwansei Gakuin Univ, Sch Sci & Technol, Dept Appl Chem Environm, Gakuen 2-1, Sanda 6691337, Japan
来源：
X-RAY STRUCTURE ANALYSIS ONLINE | 2016年 / 32卷
关键词：
D O I：
10.2116/xraystruct.32.13
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The dinuclear zinc(II) complex [Zn-2(L)(MeCO2)(2)]BPh4 [HL = 1:2 condensation product of 2,6-diformyl-4-methylphenol and 2-methoxyethylamine] was prepared, and characterized by a single-crystal X-ray method. The compound crystallized in the monoclinic space group P21/n and Z = 4 with the following cell parameters: a = 14.9150(18)angstrom, b = 10.2522(12)angstrom, c = 26.964(4)angstrom, beta = 103.127(3)degrees, V = 4015.4(9)angstrom. The R-1 [I > 2 sigma(I)] and wR(2) (all data) values were 0.0351 and 0.0631, respectively, for all 8747 independent reflections. In the complex cation, [Zn-2(L)(MeCO2)(2)], two zinc(II) ions are bridged by the phenolate oxygen of the dinucleating ligand, L-, and two acetate ions. Both zinc(II) ions have trigonal bipyramidal coordination geometry.
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页码：13 / 14
页数：2
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