PREPARATION OF MULLITE CORDIERITE COMPOSITE POWDERS BY THE SOL-GEL METHOD - ITS CHARACTERISTICS AND SINTERING

Mullite/cordierite composite powders containing different proportions of cordierite were prepared by the sol‐gel method using boehmite, colloidal silica, and Mg(NO3)2·6H2O. Mullite and cordierite sols were prepared separately and mixed to form the composite sol. Mullitization temperature depends on the cordierite content in the composite. Also, α‐cordierite crystallizes at a lower temperature in a mullite‐rich (MC20) composite. The XRD patterns of the powders calcined at 1450°C for 12 h showed that mullite and cordierite exist as two different phases, and no additional phases were observed. The IR absorbance spectra of composites showed characteristic peak corresponding to both mullite and cordierite. The sintered density of the powders increases with temperature up to 1450°C and decreases beyound the melting point of cordierite (1455°C). The microstructure of MC30 sintered at 1440°C for 3 h consisted of acicular grains, whereas in MC40 and MC50 equiaxed grain morphology was observed under similar sintering conditions. The flexural strength and Vickers hardness decreases with the increase of cordierite content in the composite. Dielectric constant and thermal expansion showed a similar behavior. Copyright © 1990, Wiley Blackwell. All rights reserved