Crystal structure of 3-[(2-acetamidophenyl)imino]-butan-2-one

被引:1
|
作者
Zhai, Feng [1 ]
Solomon, Joseph R. [1 ]
Filatov, Alexander S. [1 ]
Jordan, Richard F. [1 ]
机构
[1] Univ Chicago, Dept Chem, 5735 South Ellis Ave, Chicago, IL USA
基金
美国国家科学基金会;
关键词
crystal structure; iminoketone; hydrogen bonding;
D O I
10.1107/S2056989018000749
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, 3-[(2-acetamidophenyl)imino]butan-2-one, C12H14N2O2, the imine C=N bond is essentially coplanar with the ketone C=O bond in an s-trans conformation. The benzene ring is twisted away from the plane of the C=N bond by 53.03 (14)degrees. The acetamido unit is essentially coplanar with the benzene ring. In the crystal, molecules are connected into chains along the c axis through C-H center dot center dot center dot O hydrogen bonds, with two adjacent chains being hinged by C-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码:193 / +
页数:7
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