DIRECT ANALYSIS OF HYDROGEN-TRANSFER REACTION FROM P-BENZOSEMIQUINONE RADICAL TO P-BENZOQUINONE BY TIME-RESOLVED CIDNP METHOD

被引：1
|
作者：
AIZAWA, T
ARAKI, Y
SHINDO, K
MAEDA, K
AZUMI, T
机构：
[1] Department of Chemistry, Faculty of Science, Tohoku University, Sendai
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1994年 / 50卷 / 8-9期
关键词：
D O I：
10.1016/0584-8539(94)80077-4
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The rate constant of the hydrogen transfer reaction from p-benzosemiquinone radical to p-benzoquinone was measured by the time-resolved CIDNP technique. The time dependence of the CIDNP intensity of the products, p-benzoquinone and p-hydrobenzoquinone, can be simulated by kinetic treatment. From the simulation, the rate constant of the hydrogen transfer is obtained.
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页码：1443 / 1450
页数：8
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