SYNTHESIS OF BETA-OCTASUBSTITUTED STERICALLY BULKY PORPHYRINS BY SUZUKI CROSS-COUPLING

被引:36
|
作者
ZHOU, X [1 ]
ZHOU, ZY [1 ]
MAK, TCW [1 ]
CHAN, KS [1 ]
机构
[1] CHINESE UNIV HONG KONG,DEPT CHEM,SHA TIN,HONG KONG
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 18期
关键词
D O I
10.1039/p19940002519
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
beta-Octasubstituted tetramesitylporphyrins have been-prepared in good yields by Suzuki-cross coupling of beta-octabromotetramesitylporphyrin with aryl- and alkyl-boronic acids. A single-crystal X-ray analysis of beta-octamethyltetramesitylporphyrin 3a shows a saddled non-planar structure.
引用
收藏
页码:2519 / 2520
页数:2
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