SYNTHESIS BASED ON CYCLOHEXADIENES .11. A NEW TOTAL SYNTHESIS OF (PLUS-OR-MINUS)-NORPREZIZANONE

被引：8
|
作者：
SELVAKUMAR, N [1 ]
RAO, GSRS [1 ]
机构：
[1] INDIAN INST SCI,DEPT ORGAN CHEM,BANGALORE 560012,KARNATAKA,INDIA
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 48期
关键词：
CYCLOADDITION; STEREOSPECIFIC 1,4-ADDITION; SESQUITERPENE SYNTHESIS;
D O I：
10.1016/S0040-4039(00)61567-8
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Acid catalyzed rearrangement of endo 1-methoxytricyclo[6.2.2.0(3,8)]dodec-2-en-10-ol 8c afforded the ketone 9 which has been transformed into (+/-)-norprezizanone 19 thus completing a formal synthesis of (+/-)-zizaene. A key step in this strategy is a stereospecific 1,4-addition of a methyl group.
引用
收藏
页码：7789 / 7792
页数：4
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