CHEMILUMINESCENT REACTION OF OXYGEN-ATOMS WITH SOME NITRILE COMPOUNDS

被引：4
|
作者：
UPADHYAYA, HP
PAVANAJA, UB
SAPRE, AV
RAO, KVSR
MITTAL, JP
机构：
[1] Chemistry Division, Bhabha Atomic Research Centre, Bombay, 400 085, Trombay
来源：
CHEMICAL PHYSICS LETTERS | 1994年 / 227卷 / 4-5期
关键词：
D O I：
10.1016/0009-2614(94)00861-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In a discharge-flow experiment, chemiluminescent reactions of oxygen atoms (O(P3)) with organic nitriles (RCN) are studied. For unsaturated nitriles RCN (R: CH2=CH; CH2=C(CH3); CH2=CH(CH2)) the observed emission is attributed to CN* (B-->X) and NO* (gamma: A-->X and beta: B-->X, bands). For saturated and phenyl nitriles (R: CH3; C2H5; C6H5) emission is only observed from CN* (B2 SIGMA+). A suitable reaction mechanism for the observed emission is proposed.
引用
收藏
页码：511 / 518
页数：8
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