SYNTHESIS AND STRUCTURE OF ETA(5)-PENTAMETHYLCYCLOPENTADIENYLDICHLOROIRIDIUMTRIS(2,6-DIFLUOROPHENYL)PHOSPHITE

被引:7
|
作者
HOLLOWAY, JH
HOPE, EG
JONES, K
SAUNDERS, GC
FAWCETT, J
REEVES, N
RUSSELL, DR
ATHERTON, MJ
机构
[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND
[2] UNIV LEICESTER,CRYSTALLOG LAB,LEICESTER LE1 7RH,ENGLAND
[3] BNFL FLUOROCHEM LTD,PRESTON PR4 0XJ,ENGLAND
关键词
D O I
10.1016/S0277-5387(00)80118-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The new fluorine containing ligand, tris(2,6-difluorophenyl)phosphite, prepared from the reaction between 2,6-difluorophenol and phosphorus trichloride, reacts with eta5-pentamethylcyclopentadienyldichloroiridium dimer to give the title compound in high yield. The molecular structure of this compound has been determined by single crystal X-ray crystallography.
引用
收藏
页码:2681 / 2685
页数:5
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