ROTATIONAL-ISOMERISM OF CHLOROACETONE - SOLVENT EFFECT

被引：3
|
作者：
REDONDO, MI
GARCIA, MV
机构：
[1] Departamento Quimica Fisica I. Fac. C.C. Quimicas, Universidad Complutense
来源：
JOURNAL OF MOLECULAR LIQUIDS | 1990年 / 46卷
关键词：
D O I：
10.1016/0167-7322(90)80046-M
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Infrared absorption intensities of carbonyl bands of chloroacetone CH3COCH2Cl have been measured in solvents of different polarity at different temperatures. From these data the enthalpy difference, as well as entropy difference of the trans ⇆ gauche equilibrium, has been obtained in each solvent. The influence of solute-solvent interactions on the thermodynamic parameters of this conformational equilibrium is discussed. © 1990.
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页码：75 / 81
页数：7
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