ENERGY-EFFICIENT METHANE-TO-SYNGAS CONVERSION WITH LOW H-2/CO RATIO BY SIMULTANEOUS CATALYTIC REACTIONS OF METHANE WITH CARBON-DIOXIDE AND OXYGEN

被引：107
|
作者：
CHOUDHARY, VR
RAJPUT, AM
PRABHAKAR, B
机构：
[1] Chemical Engineering Division, National Chemical Laboratory, Pune
来源：
CATALYSIS LETTERS | 1995年 / 32卷 / 3-4期
关键词：
OXIDATION OF METHANE TO SYNGAS; CO2 REFORMING OF METHANE; NIO-CAO CATALYST; COUPLING OF EXOTHERMIC AND ENDOTHERMIC REACTIONS; REACTION OF METHANE WITH O-2 AND CO2;
D O I：
10.1007/BF00813234
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
By simultaneous reactions of methane with CO2 and O-2 over NiO-CaO catalyst under certain reaction conditions, it is possible to convert methane into syngas with low H-2/CO ratio (1 < H-2/CO < 2) at above 95% conversion, with 100% CO selectivity and above 90% H-2 selectivity and also with very high CO productivity without catalyst deactivation due to coking for a long period, in a most energy efficient and safe manner, requiring little or no external energy.
引用
收藏
页码：391 / 396
页数：6
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