SYNTHESIS AND STRUCTURE OF THE FIRST TITANIUM(IV) ALPHA-AMINO-ACID COMPLEXES

被引：36

作者：

KLAPOTKE, TM

KOPF, H

TORNIEPORTHOETTING, IC

WHITE, PS

机构：

[1] TECH UNIV BERLIN, INST ANORGAN & ANALYT CHEM, D-10623 BERLIN, GERMANY

[2] UNIV N CAROLINA, DEPT CHEM, CHAPEL HILL, NC 27599 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 14期

关键词：

D O I：

10.1002/anie.199415181

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cytostatically active titanocene dichloride reacts with α‐amino acids to give titanium(IV) amino acid complexes of the type [Cp2Ti(aa)2]2+ [Cl−]2 (aa = α‐amino acid). The structure of the cation (1) in the corresponding 2‐methylalanine complex is shown on the right. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1518 / 1519

页数：2

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