SYNTHESIS OF PHOTODEGRADABLE POLYMERS BY SH-EN POLYADDITION

被引：4
|
作者：
HAACK, V [1 ]
KLEMM, E [1 ]
机构：
[1] FRIEDRICH SCHILLER UNIV,INST ORGAN CHEM & MAKROMOLEK,HUMBOLDTSTR 10,D-07743 JENA,GERMANY
来源：
POLYMER BULLETIN | 1995年 / 34卷 / 02期
关键词：
D O I：
10.1007/BF00316390
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The polyaddition reaction of the Michael donor 1,2-bis(2-mercaptoethoxy)ethane (Bis-SH) 2 as dithiol to various Michael acceptors such as divinyl sulfone (DVS) 1, N,N'-bismaleimido-4,4'-diphenylmethane 3, 4,4'-(N-maleimido)diphenyliodoniumchloride 4 and diallyl succinate 5 in the presence of tributylamine is described. Polymers were characterized by NMR-spectroscopy, elemental analysis, DSC and TG-analysis. In particular we synthesized a photosensitive polymer with 4,4'(N-maleimido)diphenyliodonium chloride as comonomer, which eliminated analytical amounts of HCl during irradiation.
引用
收藏
页码：155 / 160
页数：6
相关论文
共 50 条
12345