VIBRATIONAL STARK-EFFECT FOR MATRIX-ISOLATED CN- MOLECULES

被引：7

作者：

SPITZER, RC ^{[1
]}

SIEVERS, AJ ^{[1
]}

SILSBEE, RH ^{[1
]}

机构：

[1] CORNELL UNIV,CTR MAT SCI,ITHACA,NY 14853

来源：

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS | 1992年 / 9卷 / 06期

关键词：

D O I：

10.1364/JOSAB.9.000978

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Stark measurements have been made on persistent IR spectral holes in the stretch mode of the CN-:Na+ center in KBr. A simple model in which the anharmonic CN- molecule is coupled harmonically to the lattice qualitatively explains both the magnitude of the zero-field frequency difference for the two molecular arrangements in the crystal as well as the absence of a Stark tuning curve for one of these configurations.

引用

页码：978 / 981

页数：4

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