RAMAN AND INFRARED-SPECTRA OF SOLID CHLOROFLUOROMETHANE

被引：3
|
作者：
SCHLUETER, SA [1 ]
DAVISON, TS [1 ]
FRASER, JM [1 ]
ANDERSON, A [1 ]
机构：
[1] UNIV WATERLOO,DEPT PHYS,WATERLOO N2L 3G1,ONTARIO,CANADA
来源：
JOURNAL OF RAMAN SPECTROSCOPY | 1994年 / 25卷 / 06期
关键词：
D O I：
10.1002/jrs.1250250609
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
Raman and infrared spectra of solid CH2ClF (Freon 31) were recorded in both the lattice and internal mode regions for samples at temperatures between 12 and 125 K. No evidence of any solid-state phase transition was found, but some thin-film samples deposited at low temperatures appear to exist in a metastable phase. Spectra of the stable phase are compatible with a non-centrosymmetric unit cell containing four molecules. Lattice peaks are assigned on the basis of geometrical and intensity arguments.
引用
收藏
页码：429 / 433
页数：5
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