NOVEL CHLOROTRIMETHYLSILANE CATALYZED STEREOSELECTIVE DECONJUGATION OF BETA-BROMO (OR IODO) SUBSTITUTED ALPHA,BETA-UNSATURATED ACYCLIC KETONE

被引：13

作者：

LUO, FT

HSIEH, LC

机构：

[1] Institute of Chemistry, Academia Sinica, Nankang, Taipei

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 51期

关键词：

D O I：

10.1016/0040-4039(94)88517-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

TMSCl catalyzed stereoselective isomerization (deconjugation) of beta-substituted alpha,beta-unsaturated ketones to the corresponding (Z)-beta,gamma-unsaturated ketones and its mechanism studies are described.

引用

页码：9585 / 9588

页数：4

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