MAGNETIC BIREFRINGENCE EFFECT IN SOLUTIONS OF PARAMAGNETIC SUBSTANCES .5. STRUCTURE OF ADDUCTS OF CERTAIN ALPHA-EPOXIDES AND KETO DERIVATIVES WITH DY(III) DIPIVALOYLMETHANATE

被引:0
|
作者
ABDULLIN, IR
VULFSON, SG
KAZAKOVA, EK
VERESHCHAGIN, AN
机构
[1] A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center
关键词
D O I
10.1007/BF00960397
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Adduct formation of Dy(DPM)3 and Eu(DPM)3 with propylene oxide, 3-carene trans-and cis-oxides, cyclohexanone, d- and l-camphor, l-alpha-bromocamphor, and DMF has been studied using paramagnetic birefringence and polarimetry. The orientation of the chelate rings in Ln(DPM)3 and the composition and structure of the adducts formed were determined.
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页码:1749 / 1754
页数:6
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