CdTe Quantum Dot Fluorescence Modulation by Spin Crossover

被引:18
|
作者
Kraieva, Olena [1 ]
Suleimanov, Iurii [1 ,2 ]
Molnar, Gabor [1 ]
Salmon, Lionel [1 ]
Bousseksou, Azzedine [1 ]
机构
[1] CNRS, Lab Chim Coordinat, 205 Route Narbonne, F-31077 Toulouse, France
[2] Natl Taras Shevchenko Univ, Dept Chem, 62a Volodymyrska St, UA-01601 Kiev, Ukraine
关键词
nanocomposite; quantum dots; luminescence; spin crossover;
D O I
10.3390/magnetochemistry2010011
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Nanocomposite materials containing Cadmium Telluride (CdTe) nanocrystals and [Fe(H-trz)(2)(trz)]BF4 nanoparticles were synthesized and investigated for the coupling between their photoluminescent and spin crossover properties. The bright CdTe emission around 550 nm was found to decrease reversibly when switching the ferrous complex from the high spin (HS) to the low spin (LS) state, which was attributed to the spectral overlap of the luminescence with the absorption of the complex in the latter electronic configuration. A significant irreversible change of the luminescence signal (photobleaching) was also observed both in emission intensity and lifetime measurements.
引用
收藏
页数:8
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